The Commodore is more refined and a better drive than the Chrysler but don't forget the excellent Falcon XR8. It's now effectively a GT and, apart from the high seating position, has very few flaws at a great price.
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I'd be looking at spark, that's more often the cause of misfires. If the plugs and leads are in good order, I would be looking at engine sensors, their connections and the wiring.
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Belts perish and stretch over time and need to be replaced even though the mileage is low in your case. We couldn't establish a recommended time, from mechanics or Chrysler dealerships, but I would suggest it would be worth changing the belt given the car is eight years old.
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